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Acid Esterification
Acid / Base is for experimenters - Serious users do it as quick and cheap as possible|
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just out of curiosity did you read thru the acid/base recipes at the top of this forum?
did you see the simplified method? the one that determines the amount of acid based on titration? you might want to give that a whorl.. I know it works for me. I think I've 3 batches this year that would qualify as 'good oil'. and that's 3 out of 50 for the most part it sounds like most of your time is spent letting the fuel settle before you wash. I done with 3-5 batches( acid/base) in the amount of time you spend settling. so maybe there's more to acid/base than you understand just yet. -dkenny '84 bluebird school bus, DD8.2L turbo 2006 Jeep Liberty CRD the Liberty is now running B100 99 dodge 2500 5.9l 24v..-mine |
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dkenny
Read a little last night, some very good results. Seems we were a little light on with the acid for high FFA,s - something to try. I'll be away at the farm for a couple weeks (not internet access) so no comm,s for a while. Very interested in the 3/27 test will give that a go this week. There is probably 1500 -2000 lt of old oil settling and between 300 – 900 processed Bio at any one time We a moving toward SVO as I think our government will either want to tax us or make it difficult to get methanol. To get resumable prices you have to buy 800lt of methanol at a time. For beginners to Bio production I’d suggest 1-2 lt tests, with both single stage and acid/ base before larger scale batches. I’d like to read of any results of yield ‘v’ material cost comparisons for the various methods. That’s what put me off originally with acid/base as I could not justify the higher methanol usage/costs, acid costs and time. Now with the price of fuel well over $1.30 Aus per litre this could make high FFA oils more competitive. Kevin |
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Kevin,
I glad to see that my strong reaction to your comment wasn't take badly.. Its just that I have made 2000 + gallons this year using acid/base processing. yields - after getting the titration to a reasonable level (3-5 KOH), my yields have been on par with oil that initially titrates between 3-5. in otherwords starting with oil in the range of 7-27 can have the same yields as oil starting with 3. of course there is the additional cost of the acid. other than additional processing time that is the only additional cost for oil that titrates up to 14 KOH, beyond 14 draining is necassary( at least that is what I have seen). if draining is needed than additional methanol is required. the methanol drained off should be recovered along with any excess in the BD and/or glycerine. I only pay $17US/Gallon of H2SO4.. what do you consider high FFA oil? is 80KOH or 44%FFA high to you? personally I have never worked with oil this bad, but have heard from someone with used my method( FATTA derived) on oil this bad. -dkenny '84 bluebird school bus, DD8.2L turbo 2006 Jeep Liberty CRD the Liberty is now running B100 99 dodge 2500 5.9l 24v..-mine |
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Welcome back, Kevin. I've had a lot of success with your method as well, and don't find it a hassle at all. Thanks for doing that work at that time.
************ Biodiesel Homebrewing and Equipment Classes: www.girlmark.com/tour Biodiesel Homebrew Guide: www.localb100.com/book.html Diary of a Mad Scientist blog http://girlmark.com/blog |
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Acid Esterification
Acid / Base is for experimenters - Serious users do it as quick and cheap as possible
